Batman vs Darth Vader

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Pfffft, Vader easily. Batman is just a rich guy that knows karate, Vader would force choke him, not even a contest.

The big debate has always been Yoda vs Superman. I say Yoda.
 
Gotta go Vader here.
Batman was always sort of the flawed good guy....racked with self doubt. Darth suffers no such doubts. Confidence and clarity of mission (plus a way cooler outfit) gets Darth Vader the win.